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SUPPLIER OF MONO ETHYLENE GLYCOL FROM DUBAI-UAE

Monoethylene Glycol-MEGMEG in Drum Packing

WHAT IS MONOETHYLENE GLYCOL – MEG ?

Monoethylene Glycol (MEG) or Ethylene glycol in its pure form, is an odorless, colorless, syrupy liquid with a sweet taste. Ethylene glycol is produced from ethylene, via the intermediate ethylene oxide. Ethylene oxide reacts with water to produce ethylene glycol according to the chemical equation. This reaction can be catalyzed by either acids or bases, or can occur at neutral pH under elevated temperatures. The highest yields of ethylene glycol occur at acidic or neutral pH with a large excess of water. Under these conditions, ethylene glycol yields of 90% can be achieved. The major by-products are the ethylene glycol oligomers diethylene glycol, triethylene glycol, and tetraethylene glycol. It is commonly known as EG and is a colorless liquid with a sweet, odorless taste.One of the most important properties of this compound is its heat transfer properties. Some systems that require low, high or constant temperatures usually use these materials. Materials have heat transfer properties of liquids or gases that are generally divided into 3 categories. One of the most important properties of this compound is its heat transfer properties. Some systems that require low, high or constant temperatures usually use these materials. Materials have heat transfer properties of liquids or gases that are generally divided into 3 categories.

1- Low temperature liquids: These materials are typically used in temperatures below 32°F (0°C) and up to -148°F (-100°C).
2-Medium temperature: Glycol such as propylene glycol (PG), ethylene glycol (EG) and 1,3 propanidol (bioglycol) are used to protect against system frost at temperatures below 32°F and can be used by adding suitable additives up to 350°F.
3- High temperature liquids: These materials are commonly used from 350°F to 662°F (350°C).

A LOOK AT THE HISTORY OF (MEG)

According to most published sources about ethylene glycol, French chemist Charles-Adolphe Wurtz (1817-1884) first prepared ethylene glycol in 1856. This scientist first treated “ethylene iodide” with the structural formula (C2H4I2) with silver acetate and then hydrolyzed the resulting “ethylene diacetate” with potassium hydroxide.”Wurtz” called his new compound “glycol” or glycol; Because these compounds have the same qualities and similarities with both ethyl alcohol (with one hydroxyl group) and glycerin (with three hydroxyl groups). In 1859, Wurtz prepared monoethylene glycol through the hydration of ethylene oxide. There appears to have been no commercial production or use of ethylene glycol before World War I; Just when this compound was synthesized from ethylene dichloride in Germany and used as a substitute for glycerol in the explosive industry. In the United States, semi-commercial production of monoethylene glycol via ethylene chlorohydrin began in 1917. The first large-scale glycol plant was built in 1925 in South Charleston, Virginia. By 1929, almost all dynamite manufacturers used ethylene glycol for their explosives. In 1937, Carbide and Carbon Chemicals Co. set up the first plant based on the Lefort process for the vapor phase oxidation of ethylene and its conversion to ethylene oxide. Carbide maintained the monopoly of the direct oxidation process until 1953 when this scientific process was commercialized.

PRODUCTION METHODS OF MONOETHYLENE GLYCOL

1- The method of producing monoethylene glycol in the industry: Ethylene glycol is produced from ethylene (ethene) through ethylene oxide as an intermediate compound. Ethylene oxide reacts according to the following chemical equation to produce ethylene glycol:

C2H4O + H2O → HO − CH2CH2 − OH

This reaction can be catalyzed by acid or base or completed at neutral pH under high temperature. The highest efficiency for the production of monoethylene glycol is at acidic or neutral pH with a large amount of water. In this condition, ethylene glycol can be obtained with an efficiency of 90%. Major side products of these reactions include oligomers of diethylene glycol, triethylene glycol and tetraethylene glycol. Separation of these oligomers and water requires a lot of energy. About 6.7 million tons of monoethylene glycol are produced annually. Using the OMEGA process, high selectivity is achieved for these glycol compounds. In the OMEGA process, first, ethylene oxide is converted to ethylene carbonate in the presence of carbon dioxide. Then this cycle is hydrolyzed in the second step with a basic catalyst to selectively produce 98% monoethylene glycol. Carbon dioxide is released again at this stage and can be re-entered into the process cycle. Carbon dioxide is produced in part of the ethylene oxide production cycle; where some of the ethylene is completely oxidized. Dimethyl oxalate can be converted into ethylene glycol with high efficiency (94.7%) by hydrogenation method in the presence of copper catalyst: Since in this method of producing monoethylene glycol, methanol is recycled, only carbon monoxide, hydrogen and oxygen are consumed.

2- The method of producing monoethylene glycol through biological pathways: In the gut of a type of silkworm called Galleria mellonella, there are bacteria that can convert polyethylene (PE) into ethylene glycol.

APPLICATIONS OF MONOETHYLENE GLYCOL 

The most important applications of monoethylene glycol are primarily used in antifreeze formulations (50%) and secondly as a raw material in the production of polyesters such as polyethylene terephthalate (PET) (40%).

1- As a cooling agent and heat transfer: the most common use of ethylene glycol is as an intermediary for heat transfer by convection in cars and cooling computers. meg chemicals are also commonly used as coolants for chilled water air conditioning systems; Where either chillers or air conditioners are placed outside the building or water must be cooled to a temperature below freezing.

In geothermal energy based heating/cooling systems, ethylene glycol is the liquid that transfers heat using a geothermal heat pump. Monoethylene glycol generally derives energy from a source (lake, ocean, water well).

The heat capacity of pure ethylene glycol is half of the heat capacity of water. Therefore, MEG reduces the specific heat capacity of water mixtures compared to pure water while providing protection against freezing and increasing the boiling point.

Mixing monoethylene glycol with water provides additional benefits for cooling and antifreeze solutions; These advantages include preventing corrosion and acid degradation as well as preventing the growth of microbes and fungi.

2- As an antifreeze: MEG in pure monoethylene glycol antifreeze freezes at about −12°C (10.4°F), but when mixed with water, the mixture freezes at lower temperatures. For example, a mixture of 60% ethylene glycol and 40% water freezes at -45°C. Diethylene glycol behaves similarly.

Depending on whether the antifreeze is ethylene glycol or propylene glycol, there is a difference in their mixing ratio. For monoethylene glycol, mixing ratios are typically 70/30 and 65/35, while propylene glycol mixing ratios are typically 35/65 and 40/60. It is important that this mixture is an excellent antifreeze solution at the lowest operating temperature.

Monoethylene glycol is used as an antifreeze liquid for car and airplane windshields, as an antifreeze in car engines.

The use of ethylene glycol not only lowers the freezing point of aqueous mixtures, but also increases their boiling point. This results in expanding the operating temperature range of fluids for heat transfer.

3- As a precursor of polymers: in the plastic industry, monoethylene glycol is an important precursor for the preparation of polyester fibers and resins. Polyethylene terephthalate, which is used in making plastic soft drink bottles, is made from ethylene glycol.

4- Other applications

Abzda agent: Ethylene glycol is used in the natural gas industry to remove water vapor mixed with natural gas before processing.

Hydrate inhibition: Ethylene glycol is a very practical and useful drying agent due to its high boiling point and its affinity for water. MEG is widely used to prevent the formation of natural gas clathrates (various hydrated forms in methane) in long multiphase pipelines that transport natural gas from gas fields over long distances to a gas processing facility. Ethylene glycol can be recovered from natural gas and reused as an inhibitor after treatment that removes water and inorganic salts. Natural gas loses a significant amount of its water volume by ethylene glycol. In this application, ethylene glycol flows down from the top of the tower and encounters a mixture of water vapor and hydrocarbon gases. Dry gas exits from the top of the tower. Glycol and water are separated and glycol is recycled. Instead of removing water, monoethylene glycol can be used to reduce the temperature in the formation of hydrates. The purity of MEG used for hydrate inhibition is typically around 80%, while the purity of triethylene glycol used for this purpose is typically 95 to over 99%.

Minor but important uses:

  • Other very minor uses of monoethylene glycol include the production of capacitors, use as an intermediate chemical in the production of 1,4-dioxane, use as an additive to prevent corrosion in cooling systems for personal computers.
  • Ethylene glycol is also used in making some vaccines.
  • It is used as a minor ingredient (1-2%) in shoe polish and also in some inks and paints.
  • Ethylene glycol is used in some cases as an agent to remove decay and treat wood to prevent the growth of fungi. In a few cases, it has been used to treat partially decayed wooden objects for display in museums. This is just one useful solution that has been successful in dealing with wooden boat rot and is relatively inexpensive.
  • Monoethylene glycol may be a minor ingredient in screen cleaning solutions, along with the main ingredient isopropyl alcohol.
  • Ethylene glycol is commonly used as a preservative for biological specimens, especially in high schools or colleges, when dissecting tissues or organs, as a safer alternative to formaldehyde.
  • Also, MEG is used as a part of water hydraulic fluid to control subsea oil and gas production equipment.
  • Ethylene glycol can be used as a protecting group in organic synthesis to protect carbonyl compounds such as ketones and aldehydes.
THIS PRODUCT IS USED TO MAKE THE FOLLOWING MATERIALS
  • Heat Transfer Liquids
  • Water-based adhesives
  • Latex paints and asphalt emulsions
  • Electrolytic capacitors
  • Leather
  • Antifreeze and antifreeze additive
  • Intermediate material in chemical reaction and polymer production
  • Solvent for the production of plastics, varnishes, paints
  • Additive to fuel, heat exchange liquids, brakes and hydraulics
  • Dehydration
  • Coupling Printing Inks
  • Textile softener
  • Solvent for pigments in finishing textile dyeing and leather
  • Raw material in agricultural material formulations
  • General Cleaners
  • Production of explosives
  • Electrolytic component
  • Moisture Preservative
  • Blue Coating
  • Preservative, rust remover and disinfectant

Properties such as shelf life, strength and hydrophobicity have caused this material to be used in many industries, which can be noted the production of polyester resins, fibers and films, allowing the physical properties of this compound to find different applications as coolant, anti-corrosion agent, dehydrated material and chemical intermediate. It should be noted that this substance is toxic and is not used in the food industry. In this industry, propylene glycol is used.

MONOETHYLENE GLYCOL (MEG) USAGE

MEG is most commonly used as chemical intermediate in the manufacture of polyester resins and textile fibers. MEG is also wildly used as automotive antifreeze due to its low freezing point when mixed with water and used as heat transfer fluids for ventilation and air-conditioning systems shown as below.

meg

MEG FOR POLYTHYLENE TEREPHALATE

Monoethylene Glycol (MEG) for Polyethylene Terephthalate is used as key raw material in manufacture of Polyethylene Terephthalate (PET) that is widely used for food and beverage packaging such as Polyester film and PET bottles which can be completely recycled and certified as safe for use in food and beverage. The purity of the raw material is important and affects the quality of PET. MEG produced by GC has a very high purity of 99.9% wt. which can be used to produce high quality PET.

PET bottles is a clear bottle containing drinking water That has acid-resistant properties and is able to effectively absorb Oxygen and Carbon dioxide popularly used to contain soft drinks.

Monoethylene Glycol-MEG

MEG FOR POLYESTER FIBERS

MEG for Polyester Fibers is the main raw material used in the manufacture of polyester fibers, which are used in clothing as well as in the textile industry. The purity of the raw material is important and affects the quality of Polyester fiber. Monoethylene Glycol-MEG produced by GC Glycol has a very high purity of 99.9% wt. which can be used to produce high quality polyester fiber. The strength of polyester fibers is comfortable to wear. Easy to maintain and clean, resistant to wrinkles and can be mixed with other fibers to add other qualities as needed.

MEG

MEG FOR ENGINE COOLANT

MEG for Engine Coolant are the main ingredient of engine coolant with a boiling point that is two times higher than water, thus increasing the boiling point of the water and slowing the evaporation of water in the cooling system.Coolant/Antifreeze cool the engine quickly and efficiently when the heat is high. When the weather is below freezing point of water, Ethylene glycol as Antifreeze shall protects the water in the engine cooling system from freezing.

Monoethylene Glycol-MEG

MEG FOR E&E

MEG is a high purity process chemical use as medium for suspending conductive salt in electrolytic capacitors or solvent for rinse semiconductor. The global monoethylene glycol market is expected to witness significant growth over the forecast period on account of its widespread applications in numerous end-use industries including consumer goods, construction, automotive, pharmaceutical, textiles, and chemical processing. Increasing demand for polyester fiber from the global textile industry has triggered increased production of monoethylene glycol (MEG) which is expected to be a major driver for market growth. Increasing application scope of polyethylene terephthalate (PET) in numerous consumer good products such as food containers and bottles is anticipated to propel demand for MEG over the next seven years.  Rapid urbanization and changing lifestyle of consumers, particularly in emerging economies including China, India, Brazil and Mexico have been driving the packaging industry which in turn is anticipated to provide impetus to MEG market over the forecast period. Owing to its superior chemical properties including high viscosity, low freezing point, and high boiling point, MEG is widely employed in the manufacture of coolants and deicing materials. Burgeoning automotive sector coupled with aircraft manufacturing units in emerging economies of Asia Pacific and Latin America is further likely to fuel market demand. However, threat of substitutes from higher glycol byproducts such as DEG and TEG coupled with high cost involved in refining of ethylene glycols is challenge MEG market over the next seven years. Potential health hazards of MEG on account of its toxic nature are further anticipated to pose a credible threat to market.

MEG IS WIDELY USED BY THE OIL AND GAS MARKETS

In wellheads and pipelines to prevent hydrate formation at pipeline conditions. In offshore deepwater gas production facilities, where the exposure to lower temperatures in subsea pipelines is common, Monoethylene Glycol-MEG is used for hydrate inhibition. Hydrate inhibition is achieved by injecting Monoethylene Glycol (MEG) to decrease the hydrate formation temperature below the operating temperature, thereby preventing hydrate blockage of the pipeline. During the gas production process, the lean glycol mixes with the produced water from the formation. The production fluid containing natural gas with associated condensate, produced water, and the injected MEG enters the production facility, where the fluids undergo phase separation. The produced fluids pass through a slug catcher and are then flashed in a three-phase production separator to separate gas, hydrocarbon liquids, and the produced water and MEG mixture, commonly known as rich MEG. The produced gas and hydrocarbon liquids are routed onshore for sales and further processing.

PRODUCTION METHOD OF MONOETHYLENE GLYCOL

Monoethylene glycol is produced from ethylene by an intermediary called ethylene oxide. In this process, EO and water will react together and ethylene glycols including MEG, DEG and TEG (triethylene glycol) will be produced, one of the interesting points about this reaction is that the reaction can be done in environments with different pH, but it is recommended to perform a higher efficiency in acidic or neutral environment with excess amounts of water. Monoethylene Glycol is produced using an intermediate called Ethylene Oxide. During this process, Ethylene Oxide reacts with water to produce MEG based on the following reaction:

C2H4O + H2O → HOCH2CH2OH

The mentioned chemical reaction can take place in environments with different pHs. More specifically, this reaction may occur in the presence of acidic or alkaline catalysts or in neutral acidity at high temperatures; while the highest yield of ethylene glycol occurs at acidic or neutral pH in the presence of large amounts of water. The major by-products of Ethylene glycol are Diethylene Glycol oligomers, Triethylene Glycol and Tetraethylene Glycol.

On the other hand, another method for producing Monoethylene Glycol has been introduced by Chinese in recent years. This new method of producing Monoethylene Glycol-MEG , utilizes gas synthesis which is produced from coal. In this process, firstly, carbon monoxide (isolated from gas synthesis) is produced by oxidation reaction with Methyl Nitrite, Dimethyl Oxalate, and then converted to Monoethylene Glycol-MEG . Methanol is recycled in the process to be used to produce more Methyl Nitrite. The only raw material for the production of MEG is synthesis gas and water.

COOLANT & HEAT TRANSFER

The above combination is mainly used for heat transfer in cars and computers. It is also used as a coolant in air conditioning systems and in geothermal systems to transmit earth heat.
  1. Tanks and barrels containing monoethylene glycol should be stored away from heat and flammable materials. Empty containers are a fire hazard.
  2. Try not to inhale the fumes and fumes from this compound. You should always wear a mask and gloves.
  3. Wear appropriate protective clothing. If swallowed, see a doctor immediately. Ethylene glycol tanks should be kept away from incompatible materials such as oxidizing agents, acids, alkalis.
  4. Keep the container tightly closed for storage. Keep the container in a dry, cool and well-ventilated place.

INVESTIGATION OF PROPERTIES OF THIS MATERILA AS ANTIFREEZE

The most well-known application of monoethylene glycol is its use in the manufacture of car antifreeols. When Monoethylene Glycol-MEG dissolves in water it breaks the hydrogen bond, it freezes at about -12°C, but when mixed with water it is not crystallized and reduces the freezing point of the mixture. For this purpose, some MEG is mixed with water and suitable corrosion inhibitor . Usually a mixture with more than 70% of this substance is not recommended. Mixtures of 50.50 are commonly used in Europe and improve temperature resistance to -40 °C, it should be noted that this material is corrosive, so corrosion inhibitors should be used to prevent corrosion.

LEADING OR PRECURSOR FOR POLYMERS

55% of monoethylene glycol consumption is spent on the production of polyester fibers and 25% Monoethylene Glycol-MEG  is used in packaging and bottles of polyethylene terephthalate or PET. In the plastics industry, Monoethylene Glycol-MEG is one of the main precursor to thermoplastic resins, which are widely used as a precursor to polyester fibers and resins. Polyethylene terephthalate (PET) used to produce plastic bottles is also produced by this material (as a precursor).
because of its high ability to absorb water, It is used in gas systems to absorb water (dihydration).

BENEFITS AND LIMITATIONS OF USE

Due to its unique properties, it is widely used in many industries, some of these properties include:

  • Has properties similar to water, which makes it immiscible with many compounds
  • A material is available and has a low price
  • Low freezing point and high boiling point that is applicable in many industrial applications
  • It has good heat portability
  • Has a high shelf life

Despite all the benefits and benefits of monoethylene glycol, there are some limitations that include:

  • Highly flammable and quickly absorbs water
  • In case of leakage from cars, there can be a risk of combustion
  • Improper disposal of this substance, especially at airports, can harm the environment
  • Its sweet taste easily attracts children and animals, which can cause serious health damage.

HANDLING AND STORAGE

Keep in cool, dry place. Keep in well ventilated space. Storage has temperature limits. NFPA class IIIB storage. Avoid prolonged or repeated contact with skin. Wash thoroughly after handling.

MSDS AND SAFETY TIPS

Monoethylene glycol is relatively toxic. If this substance is accidentally ingested, ethylene glycol is oxidized to glycolic acid, which in turn is oxidized to oxalic acid, which is highly toxic. This compound and its toxic side products first affect the central nervous system, then the heart and finally the kidneys. Sufficient amounts can be fatal if untreated. Monoethylene glycol decomposes within 10 days in air and within a few weeks in water or soil. Through the dispersion of products containing ethylene glycol, this compound enters the environment; These activities include runway ventilation at airports. While low doses of ethylene glycol show no signs of toxicity over long periods of time, ethylene glycol is extremely dangerous at near-lethal doses (1000 mg/kg/day).  Monoethylene glycol is classified as toxic and hazardous to human health and swallowing, contact with skin and eyes and breathing should be avoided. In case of contact with the skin and eyes, you should wash the site of the collision with abundant running water and if someone swallows this substance, they should drink water.

  • Product Flammability: May be flammable at high temperature.
  • Auto-ignition temperature: 398°C (748.4°F)
  • Combustion products: carbon oxides (CO, CO2)
  • Fire hazards in the presence of various substances: It is slightly flammable in front of open flames, sparks and heat. In case of electric shock, it is non-flammable.
  • Risks of explosion in the presence of various materials: Risks of product explosion due to mechanical impact: Not available. Product explosion hazards in the presence of static discharge: Not available.
  • Fire fighting instructions: Small fire: Use dry chemical powder. Large fire: Use water spray, fog or foam. Do not use a water jet.
  • Special Note on Explosion Hazards: Explosive decomposition may occur if combined with strong acids or strong bases and subjected to high temperatures.
Due to its high toxicity, its use is prohibited in the following cases:
  • Water-related equipment
  • In the manufacture and formulation of food, medicine and cosmetics
  • As antifreeze in water tanks
  • Antifreance in fire extinguishing systems

Consult with a health/safety professional for specific selection ventilation ventilate as needed to comply with exposure limit. Local exhaust ventilation recommended. Mechanical ventilation recommended personal protective equipment.

EXPOSURE CONTROLS / PERSONAL PROTECTION : Consult with a health/safety professional for specific selection ventilation ventilate as needed to comply with exposure limit. Local exhaust ventilation recommended. Mechanical ventilation recommended personal protective equipment.

Eye: splash proof chemical goggles recommended to protect against splash of product.

Gloves: protective gloves recommended when prolonged skin contact cannot be avoided. polyethylene; neoprene; nitrile; polyvinyl alcohol; natural rubber; butyl rubber.

ENVIROMENTAL RISKS

Due to the characteristics of this compound, various environmental hazards are known for the above material. In addition, as a result of the use of this compound, byproducts such as heavy metals and other organic and inorganic molecules will be produced.
MONOETHYLENE GLYCOL PACKAGING 

Monoethylene glycol packages are generally available in heavy-duty plastic or metal drums, mostly in 230 kg. Buying and selling of MEG is done in these barrels. The purity of this compound is more than 99.5%. The packaging of Shazand Arak monoethylene glycol and Marwarid petrochemicals is also possible in bulk form and transportation in the form of tankers.

TECHNICAL DATA SHEET OF MEG

CHARACTERISTICSTEST METHODUNITVALUE
PURITYASTM E – 202WT. %99.8 MIN.
DIETHYLENE GLYCOLASTM E – 202WT. %0.08 MAX.
WATER CONTENTASTM E – 203WT. %0.08 MAX
ACIDITY AS ACETIC ACIDASTM D – 1613WT. PPM10 MAX.
ASHDC – 254Agr/100mlMAX. 0.005
CHLORIDESEO - 635WT. PPM0.1 MAX.
IRONASTM E – 202WT. PPM0.1 MAX.
ALDEHYDE AS ACETALDEHYDEDC – 163CWT. PPM10 MAX.
COLOR Pt-CoASTM D – 1209Pt - Co5 MAX.
SP. GR (20/20 °C)ASTM D – 891-1.1151 - 1.1156
DISTILLATION @ 760 MM-Hg
IBPASTM D – 1078°C196 MIN.
DPASTM D – 1078°C199 MAX.
5-95 VOL % RANGEASTM D – 1078°C1 MAX.
UV TRANSMITTANCE
AT 220 nmEO –577AT %70 MIN.
AT 275 nmEO –577AT %95 MIN.
AT 350 nmEO –577AT %99 MIN.

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